Alkali attack

nounStandard termRefractories

Damage from potassium and sodium compounds that react with alumina-silica refractories and swell them apart.

Attack by alkali vapors and condensates, mainly potassium and sodium from fuels, raw materials and recycled dust, that penetrate alumina-silica refractories and form new minerals such as kalsilite and leucite with a large volume increase. The result is alkali bursting: cracking, swelling and spalling deep behind the hot face. It is common in cement preheaters and kiln inlets, blast furnace stacks, incinerators and glass regenerators, and is fought with dense, alkali-resistant castables and silicon carbide.

Heard on the job

Riser duct castable is crumbling from alkali attack, the bypass has been closed too long.

Also heard as

  • alkali bursting
  • alkali spalling