Carbon monoxide disintegration

nounStandard termRefractories

Breakdown of refractory as carbon deposits from CO gas grow inside its pores around iron oxide spots.

Failure in which carbon monoxide breaks down to carbon and carbon dioxide inside a refractory, catalyzed by iron oxide spots, in a band roughly between 400 and 700 C. The carbon grows inside pores and cracks like a wedge until the brick swells, cracks and crumbles. It threatens blast furnace stacks, direct reduction plants and other CO-rich vessels; low-iron, well-fired materials resist it, and ASTM C288 tests for it.

Heard on the job

Stack brick passed the carbon monoxide disintegration test, so the cracking is from something else, check the cooling plates.

Also heard as

  • CO disintegration
  • carbon deposition
  • carbon bursting