Molecular flow

nounStandard termVacuum

Flow regime in which molecules bounce between the walls almost without meeting each other.

The low-pressure regime where the mean free path exceeds the duct size, Knudsen number above about 0.5. Each molecule travels independently in straight lines between wall hits and leaves each wall in a random direction, so there is no suction and a pump only removes what wanders into its inlet. Conductance no longer depends on pressure: an orifice passes about 11.6 L/s per cm² of area for air at 20 °C, and long, narrow or bent lines become severe bottlenecks.

Heard on the job

We're deep in molecular flow, so that 90-degree elbow in front of the turbo is costing us half the speed.

Insider tip

In molecular flow a pump cannot pull gas toward it, so the speed you get at the chamber depends mostly on how wide and short the path to the pump is.

Also heard as

  • free molecular flow