Karl Fischer titration

nounStandard termTribology

Chemical titration that measures water in oil down to about 10 parts per million.

A lab method in which iodine reacts selectively with water; under ASTM D6304 a coulometric titrator generates the iodine electrically and counts the water present. It covers dissolved, emulsified and free water from about 10 ppm up to a few percent. Turbine and hydraulic programs commonly alarm somewhere between 100 and 500 ppm, and transformer oils far lower. The oven method keeps additives that react with the reagent from inflating the result.

Heard on the job

Karl Fischer titration came back at 900 ppm on the hydraulic, so the crackle test wasn't lying.

Also heard as

  • KF
  • KF water