Dealloying

nounStandard termCorrosion

Selective leaching of one element from an alloy, leaving a weak, porous remnant that still looks intact.

Corrosion that removes the more active element from an alloy and leaves a spongy shell of the more noble one. Dezincification of brass leaves red, porous copper plugs or layers; graphitic corrosion of gray cast iron dissolves the iron and leaves a graphite network that keeps the pipe's shape but cuts like pencil lead. Parts can hold pressure for years and then fail suddenly under a knock or a water hammer.

Heard on the job

Old cast iron main looked fine until you scraped it, dealloyed right through, you could carve it with a pocketknife.

Insider tip

Tap old cast iron or scrape it with a knife before trusting it. Graphitized pipe sounds dull and cuts soft.

Also heard as

  • selective leaching
  • dezincification
  • graphitic corrosion